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2004 FALL MEETING PROCEEDINGS

Symposium EE
Organic/Inorganic Hybrid Materials—2004

Editors: Clément Sanchez, Ulrich Schubert, Richard M. Laine, Yoshiki Chujo

MRS Proceedings Volume 847
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Suggested format for citation of papers in this volume:
List all author names: Title of article, in Organic/Inorganic Hybrid Materials—2004, edited by Clément Sanchez, Ulrich Schubert, Richard M. Laine, and Yoshiki Chujo (Mater. Res. Soc. Symp. Proc. 847, Warrendale, PA , 2005), insert paper number.

Trophy Award Winner
From Raspberry-Like to Dumbbell-Like Hybrid Colloids Through Surface-Assisted Nucleation and Growth of Polystyrene Nodules Onto Macromonomer-Modified Silica Nanoparticles EE1.1
Etienne Duguet, Stéphane Reculusa, Adeline Perro, Céline Poncet-Legrand, Serge Ravaine, Elodie Bourgeat-Lami, and Christophe Mingotaud

Novel Organosilanes for the Preparation of High Refractive Index Silicone Coatings EE1.2
Pierre M. Chevalier and Duan L. Ou

From Hybrid Films to Mesoorganized Multi-Metal-Oxide Nanocrystalline Films (M3NF), Preparation and Characterization EE2.2
Cédric Boissière, David Grosso, Bernt Smarsly, Torsten Brezesinski, Sophie Lepoutre, Lionel Nicole, J.C. Valle Marcos, Marcus Antonietti, and Clément Sanchez

Inorganic-Organic Hybrid Hierarchically Structured Methyl-Modified Silica Monoliths EE3.1
Doris Brandhuber, Nicola Hüsing, and Herwig Peterlik

Monolithic O/I-Hybrids With Hierarchically Ordered Meso- and Macropores EE3.2
Kazuki Nakanishi, Yuki Kobayashi, Tomohiko Amatani, Kazuyuki Hirao, and Tetsuya Kodaira

Mineralization of Water-in-Oil Emulsion Droplets EE3.5
Giulia Fornasieri, Stéphane Badaire, Rénal Vasco Backov, Philippe Poulin, Cécile Zakri, and Olivier Mondain-Monval

Air-Liquid Foams, Concentrated Direct Emulsion and Soft Chemistry Toward Hierarchically Organized Porous Silica Monoliths EE3.6
F. Carn, A. Colin, M.-F. Achard, and R. Backov

Silica and Hybrid Silica Gels Revisited: New Insight by Solid State Nuclear Magnetic Resonance EE4.6
Christian Bonhomme, Lydie Camus, and Florence Babonneau

Preparation of Particulate Core-Shell Metal Oxide-Polymer Nanocomposites by a Sol-Gel Approach EE5.3
Guido Kickelbick, Dieter Holzinger

Sol-Gel Silica Particles for Controlled Release Applications EE5.6
Christophe Barbé, Sandrine Calleja, Linggen Kong, Elizabeth Drabarek, Alexandra Bush, Erden Sizgek, and Kim Finnie

Formation and Reaction of Metal-Containing Nanoparticles in Organic/Inorganic Hybrid Aerogels EE5.10
Chunhua Yao and William M. Risen Jr.

In Situ SAXS/XRD on Mesoscopically Ordered Surfactant-Silica Mesophases; What Can We Learn? EE6.1
Mika Lindén, Cilaine V. Teixeira, Heinz Amenitsch, Viveka Alfredsson, and Freddy Kleitz

The Use of Multinuclear Solid State NMR for the Characterization of Siloxane-Oxide Hybrid Nanocomposites EE6.2
Christel Gervais, Beatriz Julián, Eloisa Cordoncillo, Purificación Escribano, Mark E. Smith, Florence Babonneau, and Clément Sanchez

Modification of Metal Alkoxide Precursors by Organofunctional Bidentate Ligands: Chemical Problems and Opportunities for Materials Syntheses EE7.2
Ulrich Schubert, Ulrike Bauer, Helmut Fric, Michael Puchberger, Wolfgang Rupp, and Viktoria Torma

Inorganic-Organic Hybrid Materials From Layered Double Hydroxide Structure and Their Subsequent Carbonaceous Repliqua EE7.4
Fabrice Leroux, El Mostafa Moujahid, Claudia Roland-Swanson, Laetitia Vieille, Christine Taviot-Guého, Jean-Pierre Besse, Encarnacion Raymundo-Piñero, and François Béguin

Fabrication of Nanocomposite Thin Film of Hydroxyapatite and Polyvinylalcohol and Its Ionic Conductive Properties EE8.2
Toshihiko Takaki, Kazuyuki Fukuda, and Yoshiro Tajitsu

Surface-Modified Zirconium Oxide Clusters and Their Use as Components for Inorganic-Organic Hybrid Materials EE8.6
Yu Gao, Denise Silvia Dragan, Myhedin Jupa, Franz René Kogler, Michael Puchberger and Ulrich Schubert

Synthesis and Characterization of Imide-Oligosiloxanes Hybrid Nanocomposite (Imide HYBRIMER) by Reaction of Nano Amine Modified Oligosiloxane and Dianhydride EE8.8
Tae-Ho Lee, Jeong Hwan Kim, Ji Hoon Ko, and Byeong-Soo Bae

The Synthesis and Characterization of Energy-Conducting Polymers With Pendant Inorganic Chromophores EE8.10
James H. Alstrum-Acevedo, Joseph M. DeSimone, C. K. Schauer, and John M. Papanikolas

Three Dimensional Structure and Liquid Transport Behavior of Siloxane Gels with Co-Continuous Macropores EE9.2
Haruko Saito, Kazuki Nakanishi, Kazuyuki Hirao, Hiroshi Jinnai, Kei Morisato, and Hiroyoshi Minakuchi

Macrocellular Silica Monoliths Hierarchically Textured: Mesostructured Si-HIPE Materials EE9.4
F. Carn, A. Colin, and R. Backov

Rational Design of Macrocellular TiO2 and V2O5 Monoliths Obtained Through Soft Chemistry and Air-Liquid Foams EE9.5
F. Carn, N. Steunou, A. Colin, J. Livage, C. Sanchez, and R. Backov

Hierarchical Macro-Mesoporous Silica Monolith EE9.6
Tomohiko Amatani, Kazuki Nakanishi, Kazuyuki Hirao, and Tetsuya Kodaira

Collapse of Porosity During Drying of Alkylene-Bridged Polysilsesquioxane Gels. Influence of the Bridging Group Length EE9.9
Douglas A. Loy, James H. Small, Kimberly A. DeFriend, Kennard V. Wilson Jr., McKenzie Minke, Brigitta M. Baugher, Colleen R. Baugher, Duane A. Schneider, and Kenneth J. Shea

Iron Oxide–Doped Mesostructured Silica Films EE9.13
Ralf Supplit, Nicola Hüsing, Christina Fritscher, Patrycja Jakubiak, Vadim G. Kessler, Gulaim A. Seisenbaeva, and Sigrid Bernstorff

A Novel Method for Rapid Formation of High-Ordered Self-Assembled Monolayer EE9.16
Yoshitaka Fujita, Norifumi Nakamoto, Hiroyuki Takeda, Tomoya Hidaka, Nobuo Kimura, Hiroshi Suzuki, Noriyuki Yoshimoto, and Satoshi Ogawa

LDH-DNA Nanohybrids : A Complete Biophysical Characterization EE9.18
Fabrice Leroux, Malha Ben Belkacem, Ghislain Guyot, Christine Taviot-Guého, Philippe Léone, Laurent Cario, Léa Desigaux, and Bruno Pitard

Constrainment Effects of Interleaved Organic Molecules Into Layered Double Hydroxides EE9.19
Marc Dubois, El Mostafa Moujahid, Jean-Pierre Besse, and Fabrice Leroux

Influence of TiO2 on the Pore Structure and Texture of SiO2-PDMS Hybrid Materials EE9.20
Lucía Téllez, Juan Rubio, Miguel A.Valenzuela, Fausto Rubio, Ernesto Morales, and José L. Oteo

Vanadium Oxide Nanotubes: New Synthesis Route and Mechanism of Formation EE9.24
Maguy Jaber, Nathalie Steunou, Thierry Azaïs, and Jacques Livage

Interlamellar Incorporation of Charged Polymer Nanobeads into Sodium Montmorillonite EE9.25
Svetlana Khvan, Sang-Soo Lee, and Junkyung Kim

Layered Tungsten Oxide-Based Hybrid Materials Incorporating Transition Metal Ions EE9.31
Bridget Ingham, S.V. Chong, and Jeff L. Tallon

Intercalation of n-alkylamines in the Vapor Phase Into Vanadium Pentoxide Xerogel Dispersed Into Silica Matrix EE9.32
Mariza A. Figueiredo and Herenilton P. Oliveira

Control of the Morphology of the Layered-Silicate Epoxy Nanocomposite EE9.33
Chenggang Chen and Tia Benson Tolle

The Structure of a Molybdenum Disulfide Intercalation Compound EE9.34
Ralf Brüning, Kristopher Bulmer, Rabin Bissessur, Robert I. Haines, Pravin Varma, and Stephen Emeneau

Effects of Surface Modification of Mg(OH)2 With Polysiloxane Oil and Silica Additive on the Flame Retardancy and Mechanical Properties of LDPE-Mg(OH)2 Composites EE9.35
K. Kodama, T. Hyodo, Y. Shimizu, and M. Egashira

Responsive Polymer/Clay Aerogel Composites EE9.36
Suneel Bandi and David A. Schiraldi

Morphology and Polymorph Selectivity Control in Calcium Carbonate Mineralization EE9.38
Swaminathan Sindhu, Parayil K. Ajikumar, Subbiah Jegadesan, and Suresh Valiyaveettil

Molybdenum and Tungsten Oxide Nanowires Prepared by Electrospinning EE9.46
Katarzyna M. Sawicka, Mallikarjun Karadge, and Pelagia-Irene Gouma

Ribbon Award Winner
Photo-Induced Optical and Chemical Properties of Polysilane/Inorganic Nano-Hybrids EE10.1
Kimihiro Matsukawa and Yukihito Matsuura

Crystallization of POSS in a PEG-Based Multiblock Polyurethane: Toward A Hybrid Hydrogel EE10.2
Jian Wu, Qing Ge, Kelly A. Burke, and Patrick T. Mather

Evolution of Porosity and Morphology in Alkylene-Bridged Polysilsesquioxane Xerogels as a Function of Gel Aging Time EE10.3
Douglas A. Loy, James H. Small, Kimberly A. DeFriend, Kennard V. Wilson Jr., McKenzie Minke, Brigitta M. Baugher, Colleen R. Baugher, Duane A. Schneider, and Kenneth J. Shea

Affinity Control of Aminopropylsiloxane-Based Organic/Inorganic Hybrids for Optical Sensors EE10.6
Shingo Katayama, Noriko Yamada, and Masanobu Awano

Photoluminescence-Structure Relationships in Ormosils for Integrated Optical Devices EE10.7
Rute Sá Ferreira, Celso Molina, Karim Dahmouche, Sidney Ribeiro, Rogéria R. Gonçalves, Verónica de Zea Bermudez, and Luís Dias Carlos

Synthesis of Nanomaterials in Highly Swollen Liquid Crystals EE11.1
Myriam Tokumoto, Geetarani Surendran, Eduardo Pena dos Santos, Patricia Kooyman, Hynd Remita, Laurence Ramos, and Eric Prouzet

Bioactive Organic-Inorganic Hybrid Aerogels EE12.1
Luis Esquivias, Víctor Morales-Flórez, Manuel Piñero, Nicolás de la Rosa-Fox, Julio Ramírez, José González-Calbet, Antonio Salinas, and María Vallet-Regí

Hierarchical Porous Silicas for Chromatographic Applications Obtained by Pseudomorphic Synthesis EE12.3
Anne Galarneau, Julien Iapichella, Carolina Petitto, Francesco Di Renzo, and François Fajula

Hybrid Materials Approach in the Design of Electrodes and Electrolytes for Energy Storage and Conversion EE12.4
Karina Cuentas-Gallegos, Mónica Lira-Cantú, Nieves Casañ-Pastor, Juan A. Asensio, and Pedro Gómez-Romero

Electrochemical Characterization of Phosphosilicate-Modified Nafion Membranes EE12.5
L.C. Klein and M. Aparicio

Di-Urethane Cross-Linked Poly(oxyethylene)/Siloxane Nanohybrids Doped With Eu(CF3SO3)3 EE13.1
M.C. Gonçalves, V. de Zea Bermudez, R.A Sá Ferreira, D. Ostrovskii, and L.D. Carlos

Study of Relationship Between Morphology and Mechanical Properties of SiO2-Polyacrylate Hybrid Nanocomposite EE13.2
Yi-Hsiao Kao, Wei-Fang Su, and K.C. Lin

Simulations of Organic-Tethered Silsesquioxane Nanocube Assemblies EE13.12
Xi Zhang, Elaine R. Chan, Lin C. Ho, and Sharon C. Glotzer

Two Synthetic Routes to the Formation of Tungsten Oxide Hybrid Compounds EE13.14
S.V. Chong, B. Ingham, and J.L. Tallon

Fabrication of Organic/Inorganic Nanocomposites Using Pulsed Laser Ablation of Zinc in Aqueous Solutions EE13.18
Takeshi Sasaki, Changhao Liang, Hiroyuki Usui, Yoshiki Shimizu, and Naoto Koshizaki

Femtosecond Fluorescence Studies of Auramine O in Hybrid Sol-Gel Derived Films EE13.19
P. Prosposito, A. Quatela, H. Zhang, and M. Glasb
eek

Reliability Analysis of an Inorganic-Organic Hybrid Sol-Gel Material System for Waveguiding Applications EE13.20
S. O'Brien, R.J. Winfield, A. Connell, and G.M. Crean

Structure of Nanocomposite Films of CdS Nanoparticles in a Polymer Matrix EE13.22
Tiziana Di Luccio, Bert Nickel, Francesco Antolini, Marzia Pentimalli, and Leander Tapfer

Magnetotransport Properties of Compression Molded CrO2-Polyimide Composite EE13.23
Sanjay R. Mishra, Kartik Ghosh, Joe Losby, Ted Kehl, and Ann Viano

Preparation of Intercalative Organic/MoO3 Nanohybrid Thin Films and Their VOC Gas Sensing Properties EE13.24
Ichiro Matsubara, Norimitsu Murayama, Woosuck Shin, and Noriya Izu

Ligand Control of Semiconductor Nanocrystals for Efficient Carrier Injection EE13.25
Tomohide Murase, Harumi Asami, and Itaru Kamiya

Modification and Characterization of Si-Based Nanobuilding Blocks Precursors for Hybrid Materials EE13.26
Fayna Mammeri, Najiba Douja, Christian Bonhomme, François Ribot, Florence Babonneau, and Sandra Dirè

Octadecylphosphonic Acid Self-Assembled Monolayers as Lubricant Coatings Stable in Alkaline Media EE13.28
J. Soullier, P. Tordjeman, and P.H. Mutin

Self-Assembled Monolayers of 12-Mercaptododecylphosphonic Acid on Titania Particles; Application to the Extraction of Heavy Metals EE13.29
Sébastien Anthérieu, Florence Brodard-Séverac, Gilles Guerrero, and P. Hubert Mutin

Er3+-Doped Polyether/Siloxane Hybrid Materials for Optoelectronics EE13.31
S.C. Nunes, V. de Zea Bermudez, R.A. Sá Ferreira, L.D. Carlos, E. Morales, P.V.S. Marques

Characterization of Dendrimer-Gold Nanocomposite Materials EE13.33
Lajos P. Balogh, T. Rose Ganser, and Xiangyang Shi

Evaluation of Polypyrrole Coating on Fe3O4 and Its Effect on Nanocomposite Properties EE13.34
S. Liong; A.W. Harter; R.L. Moore; and W.S. Rees Jr.

Pentacene Transistors With Polymer Gate Dielectrics on Metallized Optical Fibers EE13.40
Jimmy Granstrom and Howard E. Katz

B and P Glass Formers as Stabilizers of Luminescent Ce(III) in Silica-Based Glasses EE13.41
C. Canevali, M. Mattoni, F. Morazzoni, R. Scotti, R. Krsmanovic, S. Polizzi, M.Bettinelli, and A. Speghini

Abrasion Resistant Coatings With Ultraviolet Absorption, via Sol-Gel Dipping Method EE13.44
Nanning Arfsten, Manuel A. Alvarez, Brandon Steel, Frank Rodriguez, Hayes Rainier, and Ian Peek

Two-Dimensional Crystalline Lattice Templating: A New Method for the Preparation of Polymer-Covered Metal and Alloyed Metal Nanorods by a Redox Process EE13.45
Alexandru C. Pavel, Dwight K. Romanovicz, Miguel J. Yacaman, and John T. McDevitt

Molybdenum Dioxide and Vanadium-Doped Molybdenum Dioxide Microcrystals in a Polymer
Container EE13.46
Alexandru C. Pavel, Dwight K. Romanovicz, and John T. McDevitt

Single-Step Microstructure Patterning in Titania-Doped Sol-Gel Glassy Thin Films With Electron Beams EE13.47
Xinshi Luo, Congji Zha, and Barry Luther-Davies

Self-Extinguishing Polymer Nanocomposites EE13.52
Mayu Si, Hsinchou Chu, Daniel Hefter, Aryeh Sokolov, Jonathan Hefter, Michael Smith, Jonathan Sokolov, and Miriam Rafailovich

New High-Dielectric-Constant Polymer-Ceramic Composites EE13.58
Milind Arbatti, Xiaobing Shan, and Z.-Y. Cheng

Solution Processable Nanocomposites Based on Silsesquioxane Cores for Use in Organic Light Emitting Diodes (OLEDs) EE14.2
Alan Sellinger, Ryo Tamaki, Richard M. Laine, Kazunori Ueno, Hiroshi Tanabe, Evan Williams, and Ghassan E. Jabbour

Hybrid Materials for Optical Limiting EE14.3
Marcus Ö rtenblad, Stephane Parola, Frédéric Chaput, Cédric Desroches, Catherine Sigala, Jean Marie Létoffé, Philippe Miele, Patrice L. Baldeck, Bertil Eliasson, Anders Eriksson, and Cesar Lopes

ORMOCER®s (Organic-Inorganic Hybrid Polymers) for Telecom Applications: Structure/Property Correlations EE14.4
Frank Kahlenberg and Michael Popall



 

 








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