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2003 FALL MEETING PROCEEDINGS

Symposium L
Continuous Nanophase and Nanostructured Materials

Editors: Sridhar Komarneni, John C. Parker, James J. Watkins

MRS Proceedings Volume 788
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Formation of Nanosized Metallic Ag Grains by Oxidation of Ag Single Crystals With Hyperthermal Atomic Oxygen L1.3
Long Li and Judith C. Yang

Assembly of Nano-Domain Buildings Blocks of Copper Oxalate With a Cubic Morphology L1.4
L.C. Soare, P. Bowen, J. Lemaître, H. Hofmann, M. Pijolat, and F. Valdivieso

Molecule Derived Nanomaterials: Chemical Concepts for Composition, Morphology and Particle Size Control L1.6
Sanjay Mathur

Photo-formed Metal Nanoparticle Arrays in Monolithic Silica-Biopolymer Aerogels L2.1
Xipeng Liu, Yu Zhu, Chunhua Yao, and William M. Risen Jr.

Self Assembled Gold and Silver Nanoparticulates on Silicon Nanotips as Surface Enhanced Raman Active Substrates L2.5
S. Chattopadhyay, H.C. Lo, K.H. Chen, C.H. Hsu, L.C. Chen

Atom Probe Tomography Characterization of Thin Film Multilayers L2.8
G.B. Thompson, M.K. Miller, R. Banerjee , and H.L. Fraser

Spin-Dependent STM Tunnelling Study of the Patterned Magnetite (111) Surface L2.9
N. Berdunov, S. Murphy, G. Mariotto, and I.V. Shvets

Percolation in Multi-Wall Carbon Nanotube-Epoxy Composites-Influence of Processing Parameters, Nanotube Aspect Ratio and Electric Fields on the Bulk Conductivity L2.10
Jan K.W. Sandler, Alan H. Windle, Christian A. Martin, Matthias-Klaus Schwarz, Wolfgang Bauhofer, Karl Schulte, and Milo S.P. Shaffer

High-Resolution Analytical Electron Microscopy Investigation of Metastable Tetragonal Phase Stabilization in Undoped, Sol-Gel Derived Zirconia Nanoceramics L2.11
Vladimir P. Oleshko, James M. Howe, Satyajit Shukla, and Sudipta Seal

Photoluminescence of Si/SiO2, RE2O3/Si/SiO2 and RE2O3/Si/Al2O3 (RE = Er, Nd, Tm) Sputtered Thin Films L3.2
C. Rozo, L.F. Fonseca, O. Resto, and S.Z. Weisz

Controlled Hierarchical Pore Structures in Ethylene-Bridged Polysilsesquioxane Gels L3.10
Yuki Kobayashi, Kazuki Nakanishi, and Kazuyuki Hirao

Magnetic Properties of Nanocrystalline Fe50Co50 Powders L3.13
Shashishekar Basavaraju and Ian Baker

Fe3O4 Ultrafine Particles With Narrow Size Distribution From Polymer-Metal Complex Gels L3.17
Cheng Huang, C.Z. Yang, and L. Chen

Growth of Carbon Nanotubes Using Uniformly Distributed Cobalt Nanoparticles as Catalyst: Controlled Growth and Structural Characterization L3.19
Yoon Huh, Jeong Yong Lee, Sang Kyu Choi, and Cheol Jin Lee

Synthesis of Hydroxyapatite–Hyaluronic acid Nano Composite Sol Under Well-Controlled Condition L3.21
Yuko Ishikawa and Mamoru Senna

Preparation and Microstructure Control of Protein Thin Films Deposited by Pulsed Laser Deposition and via Colloid Chemical Routes L3.22
Sayuri Nakayama, Ichiro Taketani, Sanshiro Nagare, and Mamoru Senna

Genesis and Growth of Nanoparticles During Sol-Gel Synthesis L3.29
Nan Yao, King Lun Yeung, Guoxing Xiong, and Shishan Sheng

Incorporation of Functional Metal Oxide Materials in Chemical Microsystems L3.30
Nan Yao and King Lun Yeung

Sintered Tantalum and Niobium Sub-Micron Powders of Solid Electrolite Capacitors L3.32
Y. Pozdeev Freeman, A. Gladkikh, and Yu. Rosenberg

Structuring of Silicon Wafer Surfaces on the Sub-100 nm Scale by Hydrogen Plasma Treatments L3.34
R. Job, Y. Ma, and A.G. Ulyashin

Pulsed Laser Deposition Parameter Optimization for Growth of Alumina (Al2O3) Thin Film on Silicon (100) L3.39
Xinyu Wang, Sergey Yarmolenko, Dhananjay Kumar, Zhigang Xu, and Jagannathan Sankar

A Thermodynamic Approach in Tuning Phase Stability in Nanocomposite Multilayers L3.40
G.B. Thompson, R. Banerjee, and H.L. Fraser

In Situ Synthesis and Magnetic Properties of Polystyrene/Polypyrrole Nanocomposite Materials With Uniformly Dispersed Iron Nanoparticles L3.42
H. Srikanth, P. Poddar, J.L. Wilson, K. Mohomed, and J.P. Harmon

Microstructure of Precipitated Au Nanoclusters in TiO2 L3.45
C.M. Wang, V. Shutthanandan, Y. Zhang, D.R. Baer, L.E. Thomas, and S. Thevuthasan

Low Potential Stable Glucose Detection at Carbon Nanotube Modified Gold Electrodes L3.46
S.G. Wang, Qing Zhang, Ruili Wang, D.J. Yang, S.F. Yoon, and R. Zhang

LPE Growth of Atomically Flat Ge Layer on a Mesa Pattern L3.47
Takahiro Maruyama, Keiji Matsuda, Norikazu Saikawa, and Shigeya Naritsuka

HSA-CERCANAM®: A New Material With a Continuous Nanopore Network L4.2
A. Akash, B. Nair, K. Minnick, M. Wilson, and J. Hartvigsen

Iron Oxide/Silica Nanocomposites L4.3
Michael Kröll, Markus Pridöhl, and Guido Zimmermann

Single-Walled Carbon Nanotube Rope for Gas Sensor Application L4.4
J.W. Lee, Y.M. Choi, K.J. Kong, H.J. Chang, and B.H. Ryu

Nanocrystalline Mixed Metal Oxide--Novel Oxygen Storage Materials L4.8
Harry Sarkas, Patrick G. Murray, Aaron Fay, and R.W. Brotzman Jr.

Proton Conducting Nano Hybrid Membranes Synthesized From Temperature Tolerant Polydimethylsiloxane (PDMS) Polymers L4.10
Je-Deok Kim and Itaru Honma

Improved Tribological Properties of Diamondlike Carbon/Metal Nanocomposites L5.2
Roger J. Narayan and Dirk Scholvin

Oxygen Diffusivity and Defect Transport in Pure and Yb Doped Nano-Crystalline Ceria L5.3
Laxmikant Saraf, V. Shutthanandan, S. Thevuthasan, C.M. Wang, K.T. Koch, J.A. Andreasen, O. Marina, and Y. Zhang

Vanadium Oxide Nanofibers and Vanadium Oxide Polyaniline Nanocomposite: Preparation, Characterization and Electrochemical Behavior L5.5
Samuel T. Lutta, Hong Dong, Peter Y. Zavalij, and M. Stanley Whittingham

Achieving Electrical Percolation in Polymer-Carbon Nanotube Composites L5.8
Sameer S. Rahatekar, M. Hamm, Milo S. P. Shaffer, and James A. Elliott

Thermal and Electrical Transport Measurements of Single-Walled Carbon Nanotube Strands L5.11
Diana-Andra Borca-Tasciuc, Yann LeBon, Claire Nanot, Gang Chen, Theodorian Borca-Tasciuc, Anyuan Cao, Robert Vajtai, and Pulikel M. Ajayan

The Use of Mesoporous Systems for Preparation of One-Dimensional Ordered Magnetic Nanowires L6.1
Andrei A. Eliseev, Kirill S. Napolskii, Dmitry F. Gorozhankin, Alexei V. Lukashin, Yuri D. Tretyakov, Natalia A. Grigorieva, Sergei V. Grigoriev, and A.A. Vorobiev

Porous Carbon Nanoturf Using Anodized Alumina Templating L6.7
Ramakrishnan Rajagopalan, Krishna Dronavajjala, and Henry C. Foley

Systematic Molecular Control of Interfacial Structure in Nanoporous Carbons L6.9
Kengqing Jian, Gregory P. Crawford, Robert H. Hurt, and Nancy Y.C. Yang

Macroporous Silica and Alkylene-Bridged Polysilsesquioxane Gels With Templated Nanopores L7.5
Kazuki Nakanishi

Synthesis and Electrochemical Properties of Mesostructured 12-Phosphotungstic Acid Thin Films With Hierarchical Structures by Triblock Copolymer Templating L7.6
Hui-suk Yun, Makoto Kuwabara, Haoshen Zhou, and Itaru Honma

Mechanism of Surfactant Removal From Ordered Nanocomposite Silica Thin Films by Deep-UV Light Exposure L7.11
Andrew M. Dattelbaum, Meri L. Amweg, Julia D. Ruiz, Laurel E. Ecke, Andrew P. Shreve, and Atul N. Parikh

Carbon-Based Nanocomposite Materials for Cold Cathode Sources L8.1
Alexander V. Karabutov, Viktor G. Ralchenko, and Sergey K. Gordeev

Size Effect Characterization for Nanostructured Material in Nanoindentation Test L8.2
Yueguang Wei, Ying Du, Siqi Shu, and Chen Zhu

Preparation of Fe-Pt Nanowires Through Anodic Oxidation of Sputtered Aluminum on Glass Surface L8.4
Satoru Inoue, Song-Zhu Chu, Kenji Wada, and Yasushi Kanke

In Situ Observation of Formation Processes of Anodic Porous Alumina on a Si Substrate Using Infrared Absorption Spectroscopy L8.6
Yasuo Kimura, Hirokazu Shiraki, Hisao Ishii, Sachiko Ono, Kingo Itaya, and Michio Niwano

Synthesis of Porous Ceramics Through Directional Solidification and Freeze-Drying L8.7
Predrag Kisa, Patrick Fisher, Al Olszewski, Ian Nettleship, and Nicholas G. Eror

Effects of DC and AC Magnetic Fields on Grain Growth in Electrodeposited Nanocrystalline Nickel L8.10
T. Matsuzaki, T. Yamada, K. Jyua
mi, S. Tsurekawa, T. Watanabe, and G. Palumbo

Synthesis of Ultrafine Oxide Powders by Hydrothermal-Ultrasonic Method L8.12
Pavel E. Meskin, Yury V. Kolenko, Alexander E. Baranchikov, Vladimir K. Ivanov, Bulat R. Churagulov, Nikolay N. Oleynikov

Selective Ordered Mesoporous Silica Adsorbents L8.13
Koon Fung Lam, Ka Yee Ho, King Lun Yeung, and Gordon McKay

Macroporous Morphology Induced by Phase Separation in Sol-Gel Systems Derived From Titania Colloid L8.14
Junko Konishi, Koji Fujita, Kazuki Nakanishi, and Kazuyuki Hirao

Bramble-Like Mesostructured Nickel Oxide Fiber Clusters L8.18
Jieming Cao, Jun Wang, Jinsong Liu, Shuquan Chang, Baoqing Fang, Xianjia Ma, Xin Chang, Guoyue Xu, and Jie Tao

Characterization of Porous Silicate Low- k Films by Ellipsometric Porosimetry and Variable-Energy Positron Annihilation Spectroscopy L8.19
Kenji Ito, Yoshinori Kobayashi, Ryoichi Suzuki, Toshiyuki Ohdaira, Runsheng Yu, Kiminori Sato, Kouichi Hirata, Hisashi Togashi, Miki Egami, Hiroki Arao, Akira Nakashima, and Michio Komatsu

Mean Inner Potential of Nanostructured Noble Metal Catalysts--Pt/TiO2 Catalyst L8.21
S. Ichikawa, T. Akita, K. Okazaki, M. Okumura, K. Tanaka, and M. Kohyama

A Model of New VUV NLO Materials Based on Borate: A Novel Noncentrosymmetric Borophosphate Compound Be3BPO7 L8.23
Zhangzhen He and Hiroshi Moriyama

Mesoporous Silica Film Preparation by Novel Supercritical Fluid Extraction of Organic Templates L8.25
Nobuyuki Kawakami, Takayuki Hirano, Yoshito Fukumoto, and Yoshiyuki Nagase

Controlled Assembly of Carbon Nanotube Fibrils by Dielectrophoresis L8.27
J. Tang, G. Yang, J. Zhang, H.Z. Geng, B. Gao, O. Velev, L.-C. Qin, and O. Zhou

TEM and DOE Optimization Studies of Electrospun Polycarbonate Nanofibers L8.36
Nirupama Kattamuri and Changmo Sung

Preparation and Mechanical Properties of Nanostructured Tungsten Carbide Alloys Strengthened by Carbon Nanotubes L8.41
G.L. Tan, X.J. Wu, and Z.Q. Li

Synthesis and Characterization of Novel Organic-Inorganic Nancomposite Coatings L8.43
Brian P. Mosher and Taofang Zeng

Nano-Structured Polymer Coatings for Ultraviolet Protection L8.44
Phaneshwar Katangur, Steven B. Warner, Prabir K. Patra, Yong K. Kim, Shamal K. Mhetre, and Autumn Dhanote

Solution Electrospinning of Nylon/Ferrite Nanofibers L8.45
Autumn Dhanote, Samuel C. Ugbolue, Steven B. Warner, Prabir K. Patra, Phaneshwar Katangur, and Shamal K. Mhetre

Flame Retardancy of Laponite- and Montmorillonite-Based Nylon 6 Nanocomposites L8.46
Gunes Inan, Prabir K. Patra, Yong K. Kim, and Steven B. Warner

Carbon/Nafion® Nanocomposite Thin Films as Potential Matrix-Free Laser Desorption-Ionization Mass Spectroscopy Substrates L8.49
A. Kaan Kalkan and Stephen J. Fonash

Spherulitic Morphology and Thermal Stability of PP/ZnO Nanocomposites L8.50
Sandeep Razdan, Prabir Patra, Yong Kim, and Steve Warner

Contact Compression of Self-Assembled Nano- and Micro-scale Pyramid Structures on Au (100) Surface L8.51
J. Wang, D. Ward, W.A. Curtin, and K.-S. Kim

Hierarchically Ordered Multi-Component Block Copolymer/Particle Nanocomposite Materials L9.1
M.R. Bockstaller and E.L. Thomas

Micromechanics of PS/PB/PS Triblock-Copolymer Films with Lamellar Morphology L9.3
Theodora Tzianetopoulou and Mary C. Boyce

New Advances in Molding and Printing Processes for Organic/Plastic Electronics Using Chemically Modified Stiff, Photocured Poly (dimethylsiloxane) (PDMS) Elastomers Designed for Nano-Resolution Soft Lithography L9.6
Kyung M. Choi and John A. Rogers

Nanocomposites of Liquid Crystalline Polyhedral Oligomeric Silsesquioxane Particles and Liquid Crystalline Polymers L9.10
Alline P. Somlai, Subramanian Iyer, and David A. Schiraldi

Kinetics and Mechanism of Nucleation, Growth and Stabilization of Metal Oxide Nanoparticles L10.1
Rina Tannenbaum, Scott King, K. Hyunh, Melissa Zubris, and Nily Dan

On Molecular Dynamics Simulation of Metal Clusters and Their XRD and ELNES Spectra L10.3
G. D'Agostino and M. Gusso

Nanocomposite Material for Sensing of Halogenated Methanes: A Model Based on Charge Transfer Interaction for Selectivity L10.4
Rajiv Sangoi, L. Fuller, and K.S.V. Santhanam

Molecular Modeling Computer Simulations of Organic Polymers: A Novel Computer Simulation Technique to Characterize Nanostructured Materials L10.5
Sarah G. Schulz, Hubert Kuhn, and Günter Schmid

Exploring Space Groups for Three Dimensional Photonic Band Gap Structures Via Level Set Equations: The Face Centered Cubic Lattice L10.7
Martin Maldovan, Chaitanya K. Ullal, Craig W. Carter, and Edwin L. Thomas

Theoretical Studies of Electronic Structures and Optical Absorptions of Encapsulated Guest Alkali Metal Atoms in ITQ-4 Zeolite L10.8
Hong Li and S.D. Mahanti

Multiscale Modeling of Carbon Nanotubes L10.11
Marc Hamm, James A. Elliott, Huw J. Smithson, and Alan H. Windle

Nanostructured Oxide Films for High-Speed Humidity Sensors L11.4
John J. Steele, Kenneth D. Harris, and Michael J. Brett

Nanocomposites With Functionalized Carbon Nanotubes L11.17
Shamal K. Mhetre, Yong. K. Kim, Steven. B. Warner, Prabir. K. Patra, Phaneshwar. Katangur, and Autumn. Dhanote

Quaternary–Matrix, Nanocomposite Self-Lubricating PVD Coatings in the System TiAlCNMoS2—Structure and Tribological Properties L11.29
V. Spassov, A. Savan, A.R. Phani, M. Stueber, and H. Haefke

Structure Analysis of Co/Re Superlattice Grown on an Al2O3 (110) Substrate L11.31
Wentao Xu, Timothy Charlton, Lance E. De Long, and David Lederman

Oxidative Dehydrogenation of Ethylbenzene to Styrene Over Graphite Nanofibers L11.34
Xuejun Xu and R. Terry K. Baker

Effect of Mo Doping and Heat Treatment on Microstructure and Electrochemical Performance of Vanadium Oxide Nanotubes L11.36
Liqiang Mai, Wen Chen , Congsheng Jiang, Qing Xu, Junfeng Peng, and Quanyao Zhu

Nanodisperse Many-Particle-Systems: Concept, Structure-Property Relationships and Characterization Strategy L11.39
Vladimir P. Oleshko

Virtual Synthesis of Sub-Nanoscale Materials With Prescribed Physical Properties L11.40
Liudmila A. Pozhar, Alan T. Yeates, Frank Szmulowicz, and William C. Mitchel

Corrosion Protection of Materials by Applying Nanotechnology Associated Studies L11.44
Ramazan Asmatulu and and Richard O. Claus

UV Curable Polymers With Organically Modified Clay as the Nanoreinforcements L11.45
Fawn M. Uhl, Brian R. Hinderliter, Siva Prashanth Davuluri, Stuart G. Croll, Shing-Chung Wong, and Dean C. Webster

Structure Evolution and Corresponding Electrical Properties in Weakly Bound Co-C60 Mixture L11.49
Seiji Sakai, Hiroshi Naramoto, and Yonghua Xu

On the Development of the <111> Fiber Texture in Nanocrystalline Gold During Growth and Annealing L11.50
Klaus P. Andreasen, Norbert Schell, Thomas Jensen, Jakob H. Petersen, Martin S. Jensen, Jacques Chevallier, and J. Bøttiger

Phase Characterization and Morphology Control of Electrospun Nanofibers of PANI/PMMA Blends L11.52
K. Desai and C. Sung

Synthesis of Mesoporous Complex Framework Zirconium Phosphates via Organicinorganic Nanocomposites: Genesis of Structure, Adsorption and Catalytic Properties L11.54
Yulia V. Frolova, Vladislav A. Sadykov, S.N. Pavlova, S.A. Veniaminov, R.V. Bunina, E.B. Burgina, V.N. Kolomiichuk, T.V. Larina, N.V. Mezentseva, M.A. Fedotov, A.M. Volodin, E.A. Paukshtis, V.B. Fenelonov, R. Roy, and D. Agrawal

Nanoporous Thermosets via Reactive Encapsulation of a Chemically Inert Solvent Versus Free Radically Polymerized and Phase Separating Systems L11.55
Vijay I. Raman and Giuseppe R. Palmese

Metastable Phase Formation and Stimulated Transitions in Metallic Nanometer Films L11.57
Dirk C. Meyer, Alexandr A. Levin, Stefan Braun, Andre Gorbunov, Michael Mertig, Wolfgang Pompe, and Peter Paufler

Anomalous Magnetoresistance Behavior of Bismuth Antidot Arrays L12.1
Oded Rabin and Mildred S. Dresselhaus

Spatial Separation Mechanism in Si Quantum Dots Deposited by Chemical Vapor Deposition on SiO2 L12.2
Rosaria A. Puglisi, Giuseppe Nicotra, Salvatore Lombardo, Corrado Spinella, and Cosimo Gerardi

Synthesis and Characterization of Novel Vanadium Dioxide Nanorods L12.7
Wen Chen, Liqiang Mai, Congsheng Jiang, Junfeng Peng, Qing Xu, and Quanyao Zhu

Growth of Single Crystal Tungsten Nanorods by Oblique Angle Sputter Deposition L12.8
Tansel Karabacak, Pei-I Wang, Gwo-Ching Wang, and Toh-Ming Lu

Characterizing the Dopant Behavior of Functionalized Carbon Nanotubes in Conducting Polymers L12.11
Mark Hughes, Graeme A. Snook, George Z. Chen, Milo S. P. Shaffer, Derek J. Fray , and Alan H. Windle

Carbon Nanotubes and Nanofibers Grown by Microwave Plasma Enhanced Chemical Vapor Deposition on a Nickel Substrate L12.12
K.G. Belay, J. Jackson, and Yan Xin





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