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Volume 25, No. 9 September 2000 |
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A Publication of the Materials Research Society
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ON THE COVER: Images representing the background concept, process, and result of soft solution processing for advanced inorganic materials. Upper right: Energy diagram for the formation of BaTIO3. A huge amount of energy is necessary to create vapor, gas, or ion plasma from the solid as compared with the creation of aqueous solutions at the same temperature. This is the thermodynamic explanation for why processing of advanced materials using aqueous solutions consumes less energy in contrast to vapor/plasma processing. See the article that begins on p. 17. Upper left: Model of photoelectrochemical epitaxial growth (PEEG) on a single-crystal n-type oxide semiconductor. In the initial step, a hole created in the valence band under illumination moves to the surface and reacts with water to produce OH and/or an O- radical. The radicals immediately react with metal cations to form metal-oxide nuclei on the electrode surface. In the subsequent step, tunneling anodic current flows via surface states formed in the interface between the electrode surface and the deposited oxide nuclei, leading to epitaxial growth of the oxide. See the article that begins on p. 47. Lower left: Scanning electron microscopy observations of polyacrylate microspheres (4.5 um in diameter) that have been ferrite-coated with sonication (left) and without sonication (right), respectively, for the same time of 30 min. See the article that begins on p. 51. Images courtesy of Dr. T. Fujiwara, Tokyo Institute of Technology, Japan.
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