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The 1998 MRS Spring Meeting continued to gather momentum it entered the
third day of sessions. Along with oral presentations, the exhibit, the evening
posters as well as one tutorial kept attendees very busy. Symposium D held
a tutorial - Defects/impurities and Gettering in silicon science and technology.
Once again Symposium X had two interesting talks
at lunch time. The first on "Materials needs for semiconductors"
by Jane Shaw touched upon several materials science aspects of Semiconductors.
Shaw described the evolution of semiconductors and transistors including
the increease in the number of interconnect layers, number of transistors
and the clock frequency. She talked about requirements for polymers, optical
lithography and photoresist properties. She also briefly described the continually
decreasing width of interconnects. She suggested that understanding molecular
architecture/polymers properties as well as continual innovation in materials
is crucial for future developments of ICs. The second symposium X talk was
given by Junji Kido of Yamagata University talking about Organic electroluminescent
devices (OLEDs). He started by mentioning that nature is the most efficient
architect of organic luminescence as demonstrated in fireflies. He also
made the point that while the blue LED (using III nitrides) has received
a lot of press, blue light using electroluminescence was available 30 years
ago. The advantages of organic EL devices include large areas, low driving
voltages, fast response, high brightness and colors. He demonstrated EL
displays as part of his presentation including a 9 in display. These displays
can be used for various applications including full color displays, displays
in car radios etc. This technology clearly holds great potential.
Symposia B and C held
a joint session on field emission cathodes and displays including three
invited talks "Darpa high definition systems program" by Bruce
Gnade (DARPA), "Field emission cathode performance in thin CRTs"
by Chris Spindt et al. (Candescent Technologies) and "Development of
field emission flat panel displays" by Alec Talin (Motorola). In the
third talk, the development of a field emission display at Motorola was
described in some detail. Talin showed a video of the display showing its
clarity as well as visibility even from steep angles. Talin indicated that
field emission displays (FEDs) are better than CRTs, LCDs, plasmas or EL
displays due to various reasons including lower manufacturing costs. The
Motorola FED displays use Spindt arrays as cathodes which yield a very stable
performance after some initial degradation. Talin made the point that future
development FEDs would depend on lowering manufacturing costs including
eliminating sub micron lithography, minimizing interelectrode spacing and
reducing the need for clean rooms. Mention was also made of nanocoralline
C-N film which is coral-like carbon film with dendritic morphology of nanocrystalline
carbon. Motorola appears to be ready to bring these displays to commercialization
as soon as feasible.
In the Symposium A session on solar cells, Subhendu
Guha (United Solar Systems Corp) talked about materials issues in the commercialization
of amorphous silicon thin-film photovoltaic technology. In 1997, a record
stable cell efficiency of 13% was achieved. However for greater usage of
solar cells, the cost per watt (currently $4.50 /watt) must be lowered.
In addition, the questions of aethetics, flexibility and ruggedness must
all be addressed. Guha described various architectures and suggested that
a triple junction multibandgap structure offers the best promise of improved
efficiency. Guha also emphasized the fact that the distinction between amorphous
silicon and nanocrystalline silicon for use in solar cell applications is
dissappearing.
Symposium O, Hybrid Materials,
included a very interesting talk on "Hybrid Materials: Intricate structures
guiding complex dynamics" by Patrick Judeinstein (Laboratoire de Chemie
Structurale Organique, Orsay, France). Judeinstein described silica polymer
structures including SiO2/PEG polymers and various characterization techniques.
His presentation discussed two types of such hybrids, type I where the two
components are mixed together, and type II wherein grafting of components
is involved. Hybrids very much depend on the synergy between the organic
and inorganic components. Within this symposium O, another talk on "Enzyme
encapsulation within sol-gel glasses" by J. Livage (University of Paris)
highlighted the range of topics discussed. Sol-gel chemistry was used to
entrap biomolecules within silica matrices. While their biochemical activity
is retained, the sol-gel structure prevents leaching and the pores within
the xerogel allow small molecules to diffuse through for reaction with the
trapped enzymes. Examples of applications described included biosensors
using glucose oxidase (GOD) - silica films for measuring amount of converted
glucose, and entrapment of bacteria within silica matrices for use as enzyme
reservoirs for use as bioreactors.
Paul Holloway of the University of Florida talked about
"Advances in thin film cathodoluminescent phosphors" in Symposium
B. Thin film phosphors offer several advantages over powder phosphors
including controlled resolution, slower degradation, thermal properties
and contamination. Pulsed laser deposition of Y2O3 doped with Europium was
achieved. Good brightness including high efficiency was achieved by controlling
microstructure of the oxide.

Three poster awards were presented on this second day of
poster sessions. The awards went to :
H8.6 "A two-step low temperature process for a p-n
junction formation due to hydrogen enhanced thermal donor formationin p-type
Czochralski silicon," Reinhart Job, Wolfgang Fahrner (Univ of Hagen,
Germany), Alexander Ulyashin (Belarussian State Polytechnical Academy, Minsk).
L9.3 "In-plane anisotropy of giant magnetoresistance
in Co/Cu multilayers electrodeposited on Si(001) substrates," Matsuhiro
Shima, L. G. Salamanca-Riba (Univ of Maryland), T. P. Moffat, R. D. McMichael,
L. J. Swartzendruber (NIST).
O8.8 "Reaction engineering approach to bicomponent
alkoxysilane co-condensation," Stephen Ranking, A. V. McCormick (Univ
of Minnesota). |