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Program / MRS Symposium P
In situ Studies of Gas/Solid Surface Reaction Dynamics
Symposium Organizer Contact Info | Printable PDF version of this page

 
Chairs
Judith Yang     University of Pittsburgh
Tim Minton     Montana State University
Jeffrey A. Eastman     Argonne National Laboratory
Frances M. Ross     IBM T. J. Watson Research Center

* Invited paper

SESSION P1: Semiconductor Surface Reactions and Oxidation
Chairs: Stacey Bent and Frances Ross
Tuesday Morning, March 29, 2005
Room 3006 (Moscone West)

8:30 AM *P1.1
In-situ Observation of Oxidation Reactions at Si(001) Surfaces Using Synchrotron Radiation Photoelectron Spectroscopy. Akitaka Yoshigoe, Kousuke Moritani and Yuden Teraoka; Synchrotron Radiation Research Center, Japan Atomic Energy Research Institute, Kouto, Japan.

9:00 AM *P1.2
Real-time Monitoring of Chemical Composition, Surface Structure and Morphology, Surface Electronic State and Work Function During Thermal Oxidation on Si(001) Surfaces. Syuichi Ogawa and Yuji Takakuwa; Tohoku University, Sendai, Miyagi, Japan.

9:30 AM P1.3
A Comprehensive Study of Adsorption, Dissociation and Diffusion Processes Occurring on the PH3 Dosed Si(001) Surface. Neil Jonathan Curson1,2, Steven R. Schofield3, Oliver Warschkow1,4, Nigel A. Marks1,4, Hugh F. Wilson1,4, Marian W. Radny3, Phil V. Smith3, David R. McKenzie1,4, Thilo C. G. Reusch1,2 and Michelle Y. Simmons1,2; 1Centre for Quantum Computer Technology, University of New South Wales, Sydney, New South Wales, Australia; 2School of Physics, University of New South Wales, Sydney, New South Wales, Australia; 3School of Mathematical and Physical Sciences, University of Newcastle, Callaghan, New South Wales, Australia; 4School of Physics, University of Sydney, Sydney, New South Wales, Australia.

9:45 AM BREAK

10:15 AM P1.4
Angular Distributions of Hydrogen Molecules Produced in the Abstraction Reaction of Incident Hydrogen Atoms on Hydrogenated Si(100), Si(111) and a-Si. Regis Bisson, Laurent Philippe and Marc Chatelet; LPICM - Ecole Polytechnique, PALAISEAU, France.

10:30 AM *P1.5
Time-Dependent Behavior in the Adsorption of Model Organic Compounds on Ge(100)-2x1. Michael A. Filler, Albert Keung and Stacey Bent; Chemical Engineering Dept, Stanford University, Stanford, California.

11:00 AM P1.6
Arrangement of SiC Islands After Formation of Si(001)-c(4x4) Structure Using Monomethylsilane. Masayuki Harashima, Kanji Yasui, Masasuke Takata and Tadashi Akahane; Nagaoka University of Technology, Nagaoka, Niigata, Japan.

11:15 AM P1.7
Growth Kinetics and Relaxation Mechanism of Very Thin Epitaxial Si Films on (100) Germanium. Renaud Bonzom, Frederik Leys, Roger Loo, Olivier Richard, Danielle Vanhaeren, Jens Rip, Jan Van Steenbergen, Brice De Jaeger, Hugo Bender, Wilfried Vandervorst, Matty Caymax and Marc Meuris; IMEC, Leuven, Belgium.

11:30 AM P1.8
Synchrotron Radiation Photoemission Study of the Cs and O Co-Adsorbed InP(100) Surface for Applications in Negative Electron Affinity Devices. Dong-Ick Anthony Lee1,4, Zhi Liu3,4, Shiyu Sun3,4, Samuel P. A. Peterson2,4, William E. Spicer4 and Piero Pianetta2,4; 1Materials Science and Engineering, Stanford University, Stanford, California; 2Electrical Engineering, Stanford University, Stanford, California; 3Physics, Stanford University, Stanford, California; 4Stanford Synchrotron Radiation Laboratory, Menlo Park, California.

SESSION P2: Metal Oxidation
Chairs: Jeff Eastman and Akitaka Yoshigoe
Tuesday Afternoon, March 29, 2005
Room 3006 (Moscone West)

1:30 PM *P2.1
In-Situ Studies of the Oxidation of Strained, Coherent Cu (001) Films. Paul Fuoss, J. A. Eastman, G.-W. Zhou, L. E. Rehn, P. M. Baldo, L. J. Thompson and D. D. Fong; Materials Science Division, Argonne National Laboratory, Argonne, Illinois.

2:00 PM *P2.2
In-Situ X- Ray Measurement of Strains in Thermally Grown Oxides. Boyd W Veal1, Arvydas P. Paulikas1, Peggy Y. Hou2, Arun Reddy3, Arthur H. Heuer3, Manfred Ruhle4, Peter M. Baldo1, Robert C. Birtcher1, Guy Jennings1 and Jennifer A. Linton1; 1Argonne National Laboratory, Argonne, Illinois; 2Lawrence Berkeley National Laboratory, Berkeley, California; 3Case Western Reserve University, Cleveland, Ohio; 4Max-Planck-Institut for Metallforschung, Stuttgart, Germany.

2:30 PM P2.3
Thermal Stability and Decomposition Mechanism of Very Thin Oxide on Ti(0001) Surface Studied by Real-Time Photoelectron Spectroscopy. Yuji Takakuwa1, Syuichi Ogawa1, Masayuki Ohira1, Shinji ishidzuka2, Kousuke Moritani3, Akitaka Yoshigoe3, Yuden Teraoka3, Yoshiyuki Mizuno4, Hideki Tonda5 and Teiichi Homma6; 1Tohoku University, Sendai, Japan; 2Akita National College of Technology, Akita, Japan; 3Japan Atomic Energy Research Institute, Sayo-gun, Japan; 4Stanford University, Menlo Park, California; 5Kumamoto University, Kumamoto, Japan; 6Chiba Institute of Technology, Narashino, Japan.

2:45 PM P2.4
In Situ Oxidation and Plasma Studies for Magnetic Tunnel Junctions: The Mechanism of Plasma Oxidation of Ultra-Thin Aluminum Films Unravelled. Karel Knechten, Henk J. M. Swagten, Bert Koopmans, Wim J. M. de Jonge and Richard M.C.M. van de Sanden; Applied Physics, Eindhoven University, Eindhoven, Netherlands.

3:00 PM BREAK

3:30 PM *P2.5
Early-Stage Oxidation of Cu and Cu-Au Alloys Investigated by In Situ UHV-TEM. Guangwen Zhou1, Liang Wang2, Robert C. Birtcher1, Juditch C. Yang2, Pete M. Baldo1, John E. Pearson1 and Jeff A. Eastman1; 1Materials Science Division, Argonne National Laboratory, Argonne, Illinois; 2Department of Materials Science and Engineering, University of Pittsburgh, Pittsburgh, Pennsylvania.

4:00 PM P2.6
Energetics and Kinetics of Cu-Au Alloy Oxidation Studied by in situ UHV-TEM. Liang Wang1, Guang-Wen Zhou2, Jeff A. Eastman2 and Judith C. Yang1; 1Department of Materials Science and Engineering, University of Pittsburgh, Pittsburgh, Pennsylvania; 2Materials Science Division, Argonne National Laboratory, Argonne, Illinois.

4:15 PM P2.7
Observing the Dynamics of Metal Alloy Oxidation Using Low-Energy Electron Microscopy. Kevin F. McCarty and J. P. Pierce; Materials Physics Department, Sandia National Laboratories, Livermore, California.

4:30 PM P2.8
Observation of the Oxidation of Ru(0001) by Low-Energy Electron Microscopy. Peter Sutter1, Jan Hrbek2,1 and Robert Hwang1; 1Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York; 2Department of Chemistry, Brookhaven National Laboratory, Upton, New York.

4:45 PM P2.9
Redox Processes in Ceria and Ceria-Zirconia. Ruigang Wang3, Yong Jiang3, Renu Sharma1, James Adams3,2 and Peter A. Crozier1; 1Center for Solid State Science, Arizona State University, Tempe, Arizona; 2Chemical and Materials Engineering, Arizona State University, Tempe, Arizona; 3Science and Engineering of Materials Program, Arizona State University, Tempe, Arizona.

SESSION P3: Atomic Oxygen and Organic Materials
Chairs: Dennis Jacobs and Tim Minton
Wednesday Morning, March 30, 2005
Room 3006 (Moscone West)

8:30 AM *P3.1
Reaction of Hyperthermal Energy Oxygen Ions with Hydrocarbon Self-Assembled Monolayers. Dennis Christopher Jacobs, Tochko Tzvetkov, Xiangdong Qin and Xin Liu; Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana.

9:00 AM *P3.2
Atomic Oxygen Reactions with Self Assembled Monolayers and Polymeric Substrates. Howard Fairbrother, Chemistry, Johns Hopkins University, Baltimore, Maryland.

9:30 AM *P3.3
QM/MM Studies of Polymer Degradation by Hyperthermal Atomic Oxygen. Diego Troya, Lipeng Sun and George C. Schatz; Northwestern University, Evanston, Illinois.

10:00 AM BREAK

10:30 AM *P3.4
Atomic Beam-Surface Scattering Studies of the Combined Effects of VUV Radiation and Hyperthermal O or Ar Atoms on the Erosion of FEP Teflon Surfaces. Amy Leigh Brunsvold and Timothy K. Minton; Chemistry and Biochemistry, Montana State University, Bozeman, Montana.

11:00 AM P3.5
Deposition of Organic Thin Films Using Energy Tunable Molecular Beams. Aravind S. Killampalli, Todd W. Schroeder and J. R. Engstrom; School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, New York.

11:15 AM P3.6
Atomic-Scale Imaging of Carbon Nanofiber Growth. Bjerne S. Clausen, Stig Helveg, Jens Sehested, Poul L. Hansen and Jens R. Rostrup-Nielsen; Haldor Topsoe A/S, Nymoellevej 55, DK-2800 Kgs. Lyngby, Denmark.

11:30 AM P3.7
Fabricating Inorganic-Organic Interfaces for Use in Molecular Electronics. Abhishek Dube1, Manish Sharma1, Andrew Chadeayne2, Peter T. Wolczanski2 and James R. Engstrom1; 1School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, New York; 2Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York.

SESSION P4: Surface Reactions/Chemical Vapor Deposition
Chairs: Paul Fuoss and Renu Sharma
Wednesday Afternoon, March 30, 2005
Room 3006 (Moscone West)

1:30 PM *P4.1
Eley-Rideal and Hot Atom Reactions on Metal and Graphite Surfaces. Bret Jackson, Chemistry, University of Massachusetts, Amherst, Massachusetts.

2:00 PM *P4.2
Reduction of Oxygen on Au(100) in Base: Lessons From the Gas-Solid Interface. Andrew A. Gewirth, Chemistry, University of Illinois, Urbana, Illinois.

2:30 PM P4.3
Sulfur-Induced Corrosion of Au(111) Studied by Real-Time STM. Monika Margarete Biener1,3, Juergen Biener2 and Cynthia M. Friend1,3; 1Chemistry Department, Harvard University, Cambridge, Massachusetts; 2Nanoscale Synthesis and Characterization Laboratory, Lawrence Livermore National Laboratory, Livermore, California; 3Division of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts.

2:45 PM P4.4
In-Situ Studies of Reversible Hydriding in Palladium Thin Films. Dillon Fong, J. A. Eastman, P. H. Fuoss, G. W. Zhou, L. E. Rehn, P. Baldo and L. J. Thompson; Materials Science Division, Argonne National Laboratory, Argonne, Illinois.

3:00 PM BREAK

3:30 PM P4.5
In-Situ Observations of CO2 Mineral Sequestration Process. Renu Sharma, Michael J. McKelvy, Hamdallah Bearat, Andrew V. G. Chizmeshya and Ray W. Carpenter; Center for Solid State Science, Arizona State University, Tempe, Arizona.

3:45 PM P4.6
Ionic Conductivity of La1-xSrxCoO3-δ (x=0.1,0.2,0.5 and 0.7) Determined via Oxygen Permeation Measurements. Frederic H. B. Mertins, Dave H. A. Blank and Henny J. M. Bouwmeester; Faculty of Science and Technology & MESA+ Research Institute for Nanotechnology, Laboratory for Inorganic Materials Science, University of Twente, Enschede, Netherlands.

4:00 PM P4.7
Low Temperature Chemical Vapor Deposition Growth Kinetics of Hafnium Diboride and Zirconium Diboride from Single Source Precursors. Yu Yang1,3, Sreenivas Jayaraman1,3, Jeniffer E. Gerbi1,3, Do-Young Kim2, Gregory S. Girolami2,3 and John R. Abelson1,3; 1Dept. of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois; 2Dept. of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois; 3Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois.

4:15 PM P4.8
Cavity Ring Down Spectroscopy Investigation of Sulfur-Assisted Nanocrystalline Diamond Chemical Vapor Deposition. Madalina Buzaianu, Vladimir Makarov, Brad Weiner and Gerardo Morell; University of Puerto Rico, San Juan, PR, Puerto Rico.

P4.9
ABSTRACT WITHDRAWN

4:30 PM P4.10
Initial Growth Study of Plasma-Assisted Atomic Layer Deposition of TiN Films by in situ Spectroscopic Ellipsometry. W. M. M. Kessels, E. Langereis, S. B. S. Heil, A. Versteegh and M. C. M. Van de Sanden; Dept. of Applied Physics, Eindhoven Univ. of Technology, Eindhoven, Netherlands.

SESSION P5: Poster Session:
Chairs: Jeff Eastman and Judith Yang
Wednesday Evening, March 30, 2005
8:00 PM
Salons 8-15 (Marriott)

P5.1
Partial Oxidation of Alkanes Over Supported Metal Oxides: In-Situ DRIFT Studies. Gerald Macala, Chemistry, UCSB, Santa Barbara, California.

P5.2
Photochemical Processing of Solid Carbon Dioxide. T. Randy Dillingham, David Cornelison, Joe Dinius, Joshua Martin and Tim Porter; Physics and Astronomy, Northern Arizona University, Flagstaff, Arizona.

P5.3
Diagnostics of Hydrogen Plasma with Optical Emission Spectroscopy and in situ Silicon Probes. Szetsen Steven Lee, Chemistry, Chung Yuan Christian University, Taoyuan, Taiwan.

P5.4
The Low Temperature Initial Oxidation Stages of Cu (100) Investigated by In situ UHV-TEM. Li Sun, Xuetian Han, Liang Wang and Judith C. Yang; Materials Science and Engineering, University of Pittsburgh, Pittsburgh, Pennsylvania.

P5.5
Growth Kinetics of Germanium on (100) Germanium by Pyrolysis of Germane. Renaud Bonzom1, Frederik Leys1, Roger Loo1, Kristof Dessein2, Wilfried Vandervorst1 and Matty Caymax1; 1IMEC, Leuven, Belgium; 2Umicore, Olen, Belgium.

P5.6
TEG for CVD Surface Kinetic Studies. Yukihiro Shimogaki, Dept. of Materials Engineering, The Univ. of Tokyo, Tokyo, Japan.

P5.7
ABSTRACT WITHDRAWN

P5.8
ABSTRACT WITHDRAWN

P5.9
Thermogravimetry of Gas/Solid Interactions. Lawrence L. Cook1, Winnie Wong-Ng1 and Siu-Wai Chan2; 1Ceramics, NIST, Gaithersburg, Maryland; 2Materials Science, Columbia University, New York, New York.

P5.10
Measurements of Water Adsorption on HfO2 and ZrO2 Surfaces Using a Novel Design for Gas Adsorption Microcalorimetry. Sergey V. Ushakov, Miaojun Wang and Alexandra Navrotsky; Thermochemistry Facility and NEAT ORU, University of California at Davis, Davis, California.

P5.11
Novel Nitrogen Radical Cleaning Technique for UHV Chamber Wall. Masaru Ebihara1, Seigo Takshima2, Masaru Hori2, Shoji Den3 and Hiroyuki Kano4; 1Foresight Techno Co., LTD., 3-3-4 Minamisuna, Kohtoh-ku, Tokyo, 136-8580, Japan; 2Department of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603, Japan; 3Katagiri Engineering Co.,Ltd., 3-5-34, Tsurumi-ku, Yokohama, Kanagawa 230-0003, Japan; 4NU-EcoEngineering Co.,Ltd, Miyosi-cyo, Nishikamo-gun, Aichi 470-0201, Japan.

P5.12
Understanding of Surface Phenomena Responsible for the Selective Growth of Ge on Si over SiO2 During Molecular Beam Epitaxy. Qiming Li1, Joshua L. Krauss3, Stephen Hersee2 and Sang M. Han1; 1Chemical & Nuclear Engineering, University of New Mexico, Albuquerque, New Mexico; 2Center for High Technology Materials / Electrical Engineering and Computer Engineering, University of New Mexico, Albuquerque, New Mexico; 3Materials Science and Engineering, University of Wisconsin, Madison, Wisconsin.

P5.13
In situ and Real-Time Second Harmonic Generation During a-Si:H Thin Film Growth: Detection of Reactive Sites for SiH3 Adsorption. I. M. P. Aarts, J. J. H. Gielis, M. C. M. van de Sanden and W. M. M. Kessels; Applied Physics, Eindhoven University of Technology, Eindhoven, Noord-Brabant, Netherlands.

P5.14
Mapping Water Reactivity at Oxide Surfaces. Jorge O. Sofo1,2,3 and Elam A. Leed2,3; 1Physics, Penn State, University Park, Pennsylvania; 2Materials Research Institute, Penn State, University Park, Pennsylvania; 3Materials Science and Engineering, Penn State, University Park, Pennsylvania.

P5.15
Nonequilibrium Activated Dissociative Chemisorption: SiH4 Dissociation on Si(100). Heather L. Abbott1, David F. Kavulak2 and Ian Harrison1; 1Chemistry Department, University of Virginia, Charlottesville, Virginia; 2Chemistry Department, University of California, Berkeley, Berkeley, California.

SESSION P6/R9: Joint Session: Catalysis: In Situ and Nano-Characterization
Chairs: Juergen Janek and Judith Yang
Thursday Morning, March 31, 2005
Room 3001 (Moscone West)

8:00 AM *P6.1/R9.1
ABSTRACT WITHDRAWN

8:30 AM *P6.2/R9.2
Understanding Growth Mechanisms and Kinetics of Gas Solid Interactions at Nanoscale Using Environmental Transmission Electron Microscope. Renu Sharma, Center for Solid State Science, Arizona State University, Tempe, Arizona.

9:00 AM P6.3/R9.3
Understanding Catalysis Through Aberration-Corrected STEM and Theory. Albina Y Borisevich1, Andrew R. Lupini1, Sanwu Wang2, Sergey N. Rashkeev1,2, Sokrates T. Pantelides2,1, Karl Sohlberg3 and Stephen J. Pennycook1,2; 1Condensed Matter Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee; 2Department of Physics and Astronomy, Vanderbilt University, Nashville, Tennessee; 3Department of Chemistry, Drexel University, Philadelphia, Pennsylvania.

9:15 AM P6.4/R9.4
The Effect of Substrates/Ligands on Metal Nanocatalysts Investigated by Quantitative Z-Contrast Imaging and High Resolution Electron Microscopy. Huiping Xu1, Noel T. Nuhfer2, Laurent Menard3, Anatoly Frenkel4, Ralph Nuzzo3, Duane Johnson3 and Judith C. Yang1; 1Dept of Mat Sci & Engr, University of Pittsburgh, Pittsburgh, Pennsylvania; 2Carnegie-Mellon University, Pittsburgh, Pennsylvania; 3University of Illinois at Urbana-Champaign, Urbana, Illinois; 4Yeshiva University, New York, New York.

9:30 AM P6.5/R9.5
Surface Defects on TiO2(110): From Atomic and Electronic Structure to Catalytic Activity. Ken Taesung Park1,2, Minghu Pan2, Sergei Kalinin3, Vincent Meunier4, William Shelton4, Arthur P. Baddorf3 and E. Ward Plummer2,3; 1Physics, Baylor University, Waco, Texas; 2Physics and Astronomy, University of Tennessee, Knoxville, Tennessee; 3Condensed Matter Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee; 4Computer Science and Mathematics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee.

9:45 AM BREAK

10:15 AM *P6.6/R9.6
Seeing Catalysts at Work at High Temperatures and High Pressures, Using STM. J. W. M. Frenken1, B. L. M. Hendriksen1, M. D. Ackermann1, S. Bobaru1, O. Robach2, I. Popa2, H. Kim2 and S. Ferrer2; 1Kamerlingh Onnese Laboratory, Leiden University, Leiden, Netherlands; 2European Synchrotron Radiation Facility (ESRF), Grenoble, France.

10:45 AM P6.7/R9.7
Heterogeneous Photocatalysis of Oxidation of Acetaldehyde Using Titania Nanotubes. Huifang Xu1, Ganesh Vanamu2, Ziming Nie1, Jonathan Phillips3 and Yifeng Wang4; 1Department of Geology and Geophysics, University of Wisconsin, Madison, Wisconsin; 2Chemical and nuclear, University of New Mexico, Albuquerque, New Mexico; 3Engineering Science and Applications Division, Los Alamos National Laboratories, Los Alamos, New Mexico; 4Sandia National Laboratories, Albuquerque, New Mexico.

11:00 AM P6.8/R9.8
Ordered Arrays of Metal Nanoclusters on Oxide Surfaces. Guido Mariotto1, Nikolai Berdunov1, Shane Murphy1, Kannan Balakrishnan1, Yakob M. Mukovskii2 and Igor V. Shvets1; 1Physics, Trinity College Dublin, Dublin, Leinster, Ireland; 2MISIS, Moscow, Russian Federation.

11:15 AM P6.9/R9.9
In situ Observation of Electrode Reactions on Solid Electrolytes Probed by Microspectroscopy. Bjoern Luerssen, Holger Fischer and Juergen Janek; Physical Chemistry, Justus-Liebig-University Giessen, Giessen, Germany.

11:30 AM P6.10/R9.10
In-situ Monitoring of Oxygen Spillover Ions on Pt/YSZ Electrodes. Juergen Janek1, Bjoern Luerssen1, Holger Fischer1 and Sebastian Guenther2; 1Physical Chemistry, Justus-Liebig-University Giessen, Giessen, Germany; 2Department Chemie, Ludwig-Maximilians-Universitaet Muenchen, Muenchen, Germany.

Symposium Organizers>

Judith Yang
University of Pittsburgh
Dept. of Materials Science & Engineering
3700 O'Hara St.
Pittsburgh, PA 15261

Tel: 412-624-8613
Fax: 412-624-8069
jyang@engr.pitt.edu

Tim Minton
Montana State University
Dept. of Chemistry & Biochemistry
108 Gaines Hall
Bozeman, MT 59717

Tel: 406-994-5394
Fax: 406-994-6011
tminton@montana.edu

Jeffrey A. Eastman
Argonne National Laboratory
Materials Science Division
Bldg. 212
9700 S. Cass Ave.
Argonne, IL 60439

Tel: 630-252-5141
Fax: 630-252-4289
jeastman@anl.gov

Frances M. Ross
IBM T. J. Watson Research Center
1101 Kitchawan Rd.
Yorktown Heights, NY 10598

Tel: 914-945-1022
Fax: 914-945-2141
fmross@us.ibm.com


 


 
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